Copper (I) and silver (I) coordination frameworks involving extended bipyridazine bridges

AS Degtyarenko, PV Solntsev, H Krautscheid…

Index: Degtyarenko, Anna S.; Solntsev, Pavlo V.; Krautscheid, Harald; Rusanov, Eduard B.; Chernega, Alexander N.; Domasevitch, Konstantin V. New Journal of Chemistry, 2008 , vol. 32, # 11 p. 1910 - 1918

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Citation Number: 51

Abstract

1, 4-(Pyridazin-4-yl) benzene (bpph), a new N-donor tetradentate ligand, was prepared by inverse electron demand cycloaddition reacting 1, 4-diethynylbenzene and 1, 2, 4, 5- tetrazine. In combination with Cu (I) and Ag (I) ions, it affords coordination framework topologies that were dominated by assembly of dinuclear metal–pyridazine “secondary building blocks”[M2 (μ-pdz) 2] supporting further polymeric connectivity. In structures [Cu2 ...