Fluorodesulfurization. A new reaction for the formation of carbon-fluorine bonds

J Kollonitsch, S Marburg…

Index: Kollonitsch,J. et al. Journal of Organic Chemistry, 1976 , vol. 41, p. 3107 - 3111

Full Text: HTML

Citation Number: 55

Abstract

Discussion The chlorinolytic cleavage of carbon-sulfur (CS) bonds is well documented and a CS bond rupture effected by bromine has been suggested but no carbon-fluorine bonds have been made by this route. Compounds in the cysteine-cystine system have been converted to their 3-chloroalanine analogues. lb, c These reactions were carried out with suspensions of hydrochlorides in methylene chloride and their mechanistic relevance to ...

Related Articles:

The mechanism of serine fluorodehydroxylation: 13 C and 19 F nmr studies

[Douglas, Alan W.; Reider, Paul J. Tetrahedron Letters, 1984 , vol. 25, # 27 p. 2851 - 2854]

ω-Transaminase-catalyzed asymmetric synthesis of unnatural amino acids using isopropylamine as an amino donor

[Park, Eul-Soo; Dong, Joo-Young; Shin, Jong-Shik Organic and Biomolecular Chemistry, 2013 , vol. 11, # 40 p. 6929 - 6933]

Thermodynamics and kinetic aspects involved in the enzymatic resolution of (R, S)-3-fluoroalanine in a coupled system of redox reactions catalyzed by …

[Goncalves, Luciana P. B.; Antunes; Oestreicher, Enrique G. Organic Process Research and Development, 2006 , vol. 10, # 3 p. 673 - 677]

The mechanism of serine fluorodehydroxylation: 13 C and 19 F nmr studies

[Douglas, Alan W.; Reider, Paul J. Tetrahedron Letters, 1984 , vol. 25, # 27 p. 2851 - 2854]

More Articles...