The Journal of Organic Chemistry

Group VI metal carbonyl catalyzed reaction of ethers and acid halides

H Alper, CC Huang

Index: Alper,H.; Huang,C.-C. Journal of Organic Chemistry, 1973 , vol. 38, # 1 p. 64 - 71

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Citation Number: 50

Abstract

The reaction of acyclic and cyclic ethers with acid halides in the presence of catalytic quantities of Group VI metal carbonyls [AI (CO) 6, where 11= Cr, Mo, W] was investigated. The catalytic order of effectiveness was found to be RIO (CO)~> W (C0) s> Cr (C0) B with 310 (C0)~ being a very useful catalyst for the reaction. The group VA substituted molybdenum carbonyls, ENo (CO),[E=(C~ HS)~ P,(C6Ha) 3As] and cis-[(CeH&P] &Io-(CO) ...

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