Effects of intraligand electron delocalization, steric tuning, and excited-state vibronic coupling on the photophysics of aryl-substituted bipyridyl complexes of Ru (II)

NH Damrauer, TR Boussie, M Devenney…

Index: Damrauer, Niels H.; Boussie, Thomas R.; Devenney, Martin; McCusker, James K. Journal of the American Chemical Society, 1997 , vol. 119, # 35 p. 8253 - 8268

Full Text: HTML

Citation Number: 215

Abstract

The synthesis and photophysical characterization of a series of aryl-substituted 2, 2'- bipyridyl complexes of RuII are reported. The static and time-resolved emission properties of [Ru (dpb) 3](PF6) 2, where dpb is 4, 4'-diphenyl-2, 2'-bipyridine, have been examined and are contrasted with those of [Ru (dmb) 3](PF6) 2 (dmb= 4, 4'-dimethyl-2, 2'-bipyridine). It is shown through analysis of electrochemical data and detailed fitting of the emission ...

Related Articles:

Synthèse de composés macrocycliques comportant deux fragments coordinants séparés et différents, de type bipyrldyl-2, 2'et diphényl-2, 9 phénanthroline-1, 10.

[Chambron, Jean-Claude; Sauvage, Jean-Pierre Tetrahedron, 1987 , vol. 43, # 5 p. 895 - 904]

Synthèse de composés macrocycliques comportant deux fragments coordinants séparés et différents, de type bipyrldyl-2, 2'et diphényl-2, 9 phénanthroline-1, 10.

[Chambron, Jean-Claude; Sauvage, Jean-Pierre Tetrahedron, 1987 , vol. 43, # 5 p. 895 - 904]

A concise synthesis of 2, 4-disubstituted pyridines: A convenient synthesis of 2-bromo-4-iodopyridine via halogen dance and its successive one-pot disubstitutions

[Duan, Xin-Fang; Li, Xiang-Hong; Li, Fu-You; Huang, Chun-Hui Synthesis, 2004 , # 16 p. 2614 - 2616]

A concise synthesis of 2, 4-disubstituted pyridines: A convenient synthesis of 2-bromo-4-iodopyridine via halogen dance and its successive one-pot disubstitutions

[Duan, Xin-Fang; Li, Xiang-Hong; Li, Fu-You; Huang, Chun-Hui Synthesis, 2004 , # 16 p. 2614 - 2616]

A concise synthesis of 2, 4-disubstituted pyridines: A convenient synthesis of 2-bromo-4-iodopyridine via halogen dance and its successive one-pot disubstitutions

[Duan, Xin-Fang; Li, Xiang-Hong; Li, Fu-You; Huang, Chun-Hui Synthesis, 2004 , # 16 p. 2614 - 2616]

More Articles...