Tetrahedron letters

Palladium-catalyzed allylic alkylation of optically active α-alkenyl-α-acyloxytrialkylsilane

K Sakaguchi, T Yamada, Y Ohfune

Index: Sakaguchi, Kazuhiko; Yamada, Takeshi; Ohfune, Yasufumi Tetrahedron Letters, 2005 , vol. 46, # 30 p. 5009 - 5012

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Citation Number: 14

Abstract

Pd-catalyzed inter-and intramolecular allylic alkylations of optically active α-alkenyl-α- acyloxysilanes are described. The reactions proceeded in a regio-and stereoselective manner to give the corresponding (E)-vinylsilanes in which the ee of the starting material was completely transferred to the product.

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