Selective Functionalization of Fullerenes with N, N??Dihalosulfonamides as an N1 Unit: Versatile Syntheses of Aza [60] fulleroids and Aziridino [60] fullerenes and their …

T Nagamachi, Y Takeda, K Nakayama…

Index: Nagamachi, Toshiki; Takeda, Youhei; Nakayama, Kazuhisa; Minakata, Satoshi Chemistry - A European Journal, 2012 , vol. 18, # 38 p. 12035 - 12045

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Citation Number: 24

Abstract

Abstract Highly selective and versatile methods for the synthesis of aza [60] fulleroids and aziridino [60] fullerenes from C 60 have been developed. The reactions utilized N, N- dihalosulfonamides as an N 1 source. The photophysical, electrochemical, and thermal properties of the iminofullerenes were investigated by means of UV/Vis spectroscopy, cyclic voltammetry, and thermogravimetry, respectively. Furthermore, photovoltaic cells based ...