Electronic spectra of sulfur difluoride radicals between 295 and 495 nm observed with resonance-enhanced multiphoton ionization spectroscopy

RD Johnson, JW Hudgens

Index: Johnson, Russell D.; Hudgens, Jeffrey W. Journal of Physical Chemistry, 1990 , vol. 94, # 8 p. 3273 - 3276

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Citation Number: 17

Abstract

Spectra of the SF2 radical were observed between 295 and 495 nm by 2+ I, 2+ 2, and 3+ 1 resonance-enhand multiphoton ionization (REMPI) spectroscopy. Vibrational progressions associated with two Rydberg states were assigned. The b IB,(4s) Rydberg state was characterized with the spectroscopic values w',(al sym str)= 991 (12) cd, d2 (al bend)= 361 (24) cd, and To= 54433 cm-I. The E (4p) Rydberg state was charactericed by the values w' ...