Unprecedented zwitterionic iminium-chalcogenide bridging ligands in diiron complexes

L Busetto, F Marchetti, S Zacchini, V Zanotti

Index: Kantlehner, Willi; Hauber, Michael; Vettel, Markus Advanced Synthesis and Catalysis, 1996 , vol. 338, # 5 p. 403 - 413

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Citation Number: 23

Abstract

... Volume: Page: ... Conversely, complexes [Fe 2 {μ-η 1 :η 3 -C(R') CHC N(Me)(R)}(μ-CO)(CO)(Cp) 2 ][SO 3 CF 3 ], 1f−h,m,n, react with S 8 /NaH, giving selectively the five-membered metallacycles [Fe(Cp)(CO){C(R')C(H)C{N(Me)(R)}S}] [R = Me, R' = Me, 7a ... 5 figure ...