… platinum metal phosphathia complexes: crystal structures of cis-[RuCl 2 (RSC 2 H 4 SR)]· 0.75 Et 2 O and cis-[RhCl 2 (RSC 2 H 4 RS)] PF 6· CH 2 Cl 2 (R= Ph 2 PCH …

NR Champness, RJ Forder, CS Frampton…

Index: Champness, Neil R.; Forder, Robin J.; Frampton, Christopher S.; Reid, Gillian Journal of the Chemical Society - Dalton Transactions, 1996 , # 7 p. 1261 - 1266

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Citation Number: 11

Abstract

Reaction of [RuCl2 (py) 4](py= pyridine) with 1 molar equivalent of the new tetradentate acyclic phosphathia compound RSC2H4SR (Ph2PCH2CH2SCH2CH2SCH2CH2PPh2) or the macrocycle meso-Ph2 [14] aneP2S2 (4, 8-diphenyl-1, 11-dithia-4.18- diphosphacyclotetradecane) in refluxing toluene under a nitrogen atmosphere afforded the ruthenium (II) complexes [RuCl2 (RSC2H4SR)] and [RuCl2 (Ph2 [14] aneP2S2)] ...