Heterogeneous Palladium Catalysts Applied to the Synthesis of 2??and 2, 3??Functionalised Indoles
L Djakovitch, V Dufaud, R Zaidi
Index: Djakovitch, Laurent; Dufaud, Veronique; Zaidi, Rabah Advanced Synthesis and Catalysis, 2006 , vol. 348, # 6 p. 715 - 724
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Citation Number: 94
Abstract
Abstract Heterogeneous palladium catalysts ([Pd (NH 3) 4] 2+/NaY and [Pd]/SBA-15) were applied to the synthesis of 2-functionalised indoles, giving generally high conversions and selectivities (> 89% yield) using only 1 mol%[Pd]-catalyst under standard reaction conditions (polar solvent, 80 C). For the synthesis of 2, 3-functionalised indoles by cross-coupling arylation, the [Pd]/SBA-15 catalyst was found to be particularly interesting, producing the ...
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