Synthesis and acetolysis of mixed trialkyl phosphites

ES Huyser, JA Dieter

Index: S Huyser,E.; Dieter,J.A. Journal of Organic Chemistry, 1968 , vol. 33, # 11 p. 4205 - 4210

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Citation Number: 13

Abstract

A number of mixed trialkyl phosphites were prepared by reaction of the appropriate mono-or dialkyl chlorophosphite and alcohol in an inert solvent in the presence of N, N- dimethylaniline. Reaction of these mixed trialkyl phosphites with acetic acid at 125'resulted in formation of a mixture of acetate esters and dialkyl phosphites. Analysis of the acetate esters produced in this manner served as a means of determining the nature of the ...