Effects of hydrogen chloride addition to the direct reaction of methylene chloride with elemental silicon
SH Yeon, JS Han, BR Yoo, IN Jung
Index: Yeon, Seung Ho; Han, Joon Soo; Yoo, Bok Ryul; Jung, Il Nam Journal of Organometallic Chemistry, 1996 , vol. 516, # 1-2 p. 91 - 95
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Citation Number: 16
Abstract
Direct synthesis of bis (chlorosily) methanes has been reinvestigated by reacting elemental silicon simultaneously with methylene chloride and hydrogen chloride in the presence of copper catalyst using a stirred reactor equipped with a spiral band agitator at a carefully controlled temperature between 260 and 340° C. Bis (dichlorosily) methane and (dichlorosily)(trichlorosily) methane were obtained as the major products and bis ( ...
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