Copper??Catalyzed Vinylsilane Allylation

…, S Vercruysse, A Sanhadji, O Riant

Index: Cornelissen, Loic; Vercruysse, Sebastien; Sanhadji, Ayoub; Riant, Olivier European Journal of Organic Chemistry, 2014 , vol. 2014, # 1 p. 35 - 38

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Citation Number: 5

Abstract

Abstract Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper (I) salt, and this led to the formation of polysubstituted 1, 4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes.

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