Claisen Orthoester Rearrangement Reaction with Secondary and Tertiary Allylic Alcohols: Synthesis of 1, 2 Secochrysanthemates and Their Structural Analogues

…, AA Arbale, GS Joshi, GH Kulkarni

Index: Kelkar, S.V.; Arbale, A.A.; Joshi, G.S.; Kulkarni, G.H. Synthetic Communications, 1990 , vol. 20, # 6 p. 839 - 847

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Citation Number: 9

Abstract

Abstract A simple route is described for the synthesis of 1, 2 Seco-chrysanthemic acid and their structural analogues, employing Claisen orthoester rearrangement reaction in the key- step of synthesis. These acids have been prepared with a view to evaluating some of the esters prepared from them for possible insecticidal and other biological properties.