Intramolecular. alpha.-amidoyl-to-aryl 1, 5-hydrogen atom transfer reactions. Heteroannulation and. alpha.-nitrogen functionalization by radical translocation

V Snieckus, JC Cuevas, CP Sloan, H Liu…

Index: Snieckus; Cuevas; Sloan; Liu; Curran Journal of the American Chemical Society, 1990 , vol. 112, # 2 p. 896 - 898

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Citation Number: 134

Abstract

When the generation of oxygen-centered radicals at remote sites is followed by intramolecular hydrogen atom transfer, a powerful method to functionalize organic molecules results2 This strategy has recently been extended to the tin hydride method by generating carbon-centered radicals at remote sites (such as protecting groups) and translocating these radicals by 1, 5-hydrogen atom transfer prior to~ yclization.~ In ...

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