Canadian Journal of Chemistry

5, 6-DIMETHYLBENZ [a] ANTHRACENE AND 5, 6-DIMETHYLBENZO [c] PHENANTHRENE

PMG Bavin

Index: Bavin,P.M.G. Canadian Journal of Chemistry, 1962 , vol. 40, p. 1399 - 1402

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Citation Number: 1

Abstract

The synthesis of benzo[c]phenanthre~~e and its derivatives has presented interesting problems, largely overcome by the use of partially hydrogenated intermediates (1, pp. 158-160; 2; 3). The successful ring expansion of benzo[c]fluorenone by the Schmidt reaction (4) and our earlier worl; with benzo[b]fluorene (5) prompted experi~nents with benzo[c]fluorene. 7-Acetylbenzo[c]fluorene (Ia) was prepared by the Claisen ...

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