Synlett

Pyrrolidine-Catalyzed Homo-Aldol Condensation Reactions of Aldehydes

T Ishikawa, E Uedo, S Okada, S Saito

Index: Ishikawa, Teruhiko; Uedo, Eiji; Okada, Siho; Saito, Seiki Synlett, 1999 , # 4 p. 450 - 452

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Citation Number: 21

Abstract

Abstract: The first example of synthetically useful pyrrolidine-catalyzed homocoupling reaction of aliphatic aldehydes accelerated by benzoic acid is presented together with a plausible reaction mechanism. Key words: homo-aldol condensation, a, b-unsaturated aldehyde, pyrrolidine catalysis, reverse Michael addition

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