Evidence for the Transient Existence of 1, 2-Dinitrosoalkenes1

FB Mallory, A Cammarata

Index: Mallory,F.B.; Cammarata,A. Journal of the American Chemical Society, 1966 , vol. 88, p. 61 - 64

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Citation Number: 56

Abstract

Abstract: Rates and activation parameters have been measured for the kinetically first-order interconversions in solution of the two methylphenylfurazan oxides and also the two ethylmethylfurazan oxides. Nmr spectral data were used to assign structures to these N- oxides. The kinetic results together with some energy calculations are interpreted as evidence for an interconversion mechanism that involves ring opening of the furazan ...