Thermal and photosensitized dimerizations of cyclohexadiene

D Valentine, NJ Turro…

Index: Valentine,D. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 5202 - 5208

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Citation Number: 107

Abstract

[CONTRIBUTION h'o. 31 13 FROM THE GATES AND CRELLIN LABORATORIES ... PASADENA, CALIFORSIA] Thermal and Photosensitized Dimerizations of Cyclohexadiene ... JR.,'~ AND GEORGE S. HAMMOND RECEIVED JASUARY 20, 1964 ... Photosensitized dimerization of 1,3-cyclohexadiene gives 9OYc yields of trans-cis-t~ans-tricyclo[6.4.0.0*~~]- dodeca-3,ll-diene (3), the corresponding cis-cis-cis-isomer (4), and exo-dicyclohexadiene (2) in 3 : 1 : 1 ...