Chemical reactions of tetramesityldisilene

…, DJ De Young, R West, J Michl

Index: Fink, Mark J.; DeYoung, Douglas J.; West, Robert; Michl, Josef Journal of the American Chemical Society, 1983 , vol. 105, # 4 p. 1070 - 1071

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Citation Number: 103

Abstract

In many addition reactions, 1 is much more reactive than normal olefins. Thus 1 adds alcohols and water (the latter in THF as cosolvent) at 50" C without catalysis to give the adducts 6 and adds ketones in a thermal reaction yielding the 1, 2-disilaoxetanes 7.8, 9 With oxygen, 1 is converted to the 1, 3-dioxetane SI0 in a reaction reminiscent of ozonolysis of olefins. Compound 8 appears to be the first example of a cyclodisiloxane. Compound 1 is ...