Synthetic Communications

A Reductive 1, 2 Transposition of Acyclic Ketones

GL Larson, LM Fuentes

Index: Larson,G.L.; Fuentes,L.M. Synthetic Communications, 1979 , vol. 9, p. 841 - 844

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Citation Number: 11

Abstract

Abstract Earlier we noted that the hydroboration of the trimethylsilyl enol ether of an acyclic ketone results in an elimination of a trimethylsiloxyborane moiety with the subsequent formation of an olefin. 1, 2 The olefin formed then undergoes hydroboration giving a monoalcohol upon oxidation.(eq 1) We wish to report here on the utility of this sequence, illustrated in eq 1, in the reductive 1, 2 transposition of acyclic ketones. 3

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