Synthesis and characterization of bidentate NHC–Pd complexes and their role in amination reactions

…, İ Özdemir, B Çetinkaya, H Arslan, D VanDerveer

Index: Demir, Serpil; Oezdemir, Ismail; Cetinkaya, Bekir; Arslan, Hakan; VanDerveer, Don Polyhedron, 2011 , vol. 30, # 1 p. 195 - 200

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Citation Number: 19

Abstract

The new well-defined and air-stable ortho-xylyl-linked N-heterocyclic carbene (NHC) Pd complexes (2a–d) have been synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, IR spectroscopy, and single crystal X-ray diffraction studies. The palladium atom in the complex 2a lies on a crystallographic mirror plane and can be described as having a square-planar coordination environment with the carbene atoms of the ...