Addition of boron trifluoride complexes of organocopper reagentsto aldimines containing α-hydrogens
M Wada, Y Sakurai, K Akiba
Index: Wada, Makoto; Sakurai, Yoji; Akiba, Kin-ya Tetrahedron Letters, 1984 , vol. 25, # 10 p. 1079 - 1082
Full Text: HTML
Citation Number: 47
Abstract
RCu · BF 3 , generated in situ from Grignard reagents, CuI, and BF 3 · OEt 2 , added to aldimines containing α-hydrogens to afford secondary amines in good yields. Boron trifluoride complex of dialkylcuprate gave essentially the same result with wider application. ... Bull. Soc. Chim. Fr. (952), p. 1964 J. Org. Chem., 45 (1980), p. 1515 J. Am. Chem. Soc., 104 (1982), p. 2081 this paper describes proton abstraction of ketimines with sec-butyllithium.
Related Articles:
[Katritzky, Alan R.; Hong, Qingmei; Yang, Zhijun Journal of Organic Chemistry, 1994 , vol. 59, # 26 p. 7947 - 7948]
[Katritzky, Alan R.; Hong, Quingmei; Yang, Zhijun Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3405 - 3408]