Chemistry Letters

A convenient method for the preparation of α-alkylated vinylic sulfones and their conversion to allylic sulfones

K Inomata, Y Tanaka, S Sasaoka, H Kinoshita…

Index: Inomata, Katsuhiko; Tanaka, Yuhji; Sasaoka, Shin-ichi; Kinoshita, Hideki; Kotake, Hiroshi Chemistry Letters, 1986 , p. 341 - 344

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Citation Number: 8

Abstract

2-Pyrrolidinoalkyl p-tolyl sulfones, which were readily available by the addition of pyrrolidine to vinylic or allylic sulfones, were converted to the corresponding α-alkylated vinylic sulfones through α-alkylation followed by elimination of pyrrolidino group. Some of the α-alkylated vinylic sulfones were further transformed to the corresponding allylic sulfones.

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