Kinetics of (Porphyrin) manganese (III)??Catalyzed Olefin Epoxidation with a Soluble Iodosylbenzene Derivative

JP Collman, L Zeng, HJH Wang, A Lei…

Index: Collman, James P.; Zeng, Li; Wang, Hong J. H.; Lei, Aiwen; Brauman, John I. European Journal of Organic Chemistry, 2006 , # 12 p. 2707 - 2714

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Citation Number: 19

Abstract

Abstract We examined the kinetics of a well-behaved system for homogeneous porphyrin- catalyzed olefin epoxidation with a soluble iodosylbenzene derivative 1 as the terminal oxidant and Mn (TPFPP) Cl (2) as the catalyst. The epoxidation rates were measured by using the initial rate method, and the epoxidation products were determined by gas chromatography. The epoxidation rate was found to be first order with respect to the ...