The Journal of Organic Chemistry

Synthesis of. alpha.,. alpha.-dichlorosulfenyl chlorides

WG Phillips, KW Ratts

Index: Phillips,W.G.; Ratts,K.W. Journal of Organic Chemistry, 1971 , vol. 36, p. 3145 - 3149

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Citation Number: 13

Abstract

As can be seen in Table I, several a-carbamoyl S-benzyl sulfides gave dichlorosulfenyl chlorides in good yield. Chlorine was an adequate substitute for sulfuryl chloride. The products here were easily obtained in a pure state and were stable pale yellow to white solids. They were characterized by their elemental analysis and nmr spectra. Their nmr spectra are interesting in that they suggest a large barrier to rotation around the NC bond; ...