The Journal of Organic Chemistry

1, 2-and 1, 4-addition in the reactions of carbonyl compounds with 1, 3-butadiene induced by cerium (IV) ammonium nitrate

E Baciocchi, R Ruzziconi

Index: Baciocchi, Enrico; Ruzziconi, Renzo Journal of Organic Chemistry, 1986 , vol. 51, # 10 p. 1645 - 1649

Full Text: HTML

Citation Number: 61

Abstract

Results Acetone, 2-butanone, and 3-methyl-2-butanone were made to react with CAN and 1, 3-butadiene, the solvent being the reactant ketone in each case. The CAN: 1, 3-butadiene molar ratio was 1: 2. Solvents different than the reactant ketones were also used but with worse results. Accordingly, in CH&N reactions were exceedingly slow, and in MeOH extensive solvolysis of the reaction products was observed.

Related Articles:

Cyclodehydration of cis–2-butene-1, 4-diol with active methylene compounds catalyzed by a diphosphinidenecyclobutene-coordinated palladium complex

[Murakami, Hiromi; Matsui, Yukio; Ozawa, Fumiyuki; Yoshifuji, Masaaki Journal of Organometallic Chemistry, 2006 , vol. 691, # 14 p. 3151 - 3156]

Improved selectivity in the preparation of some 1, 1-difunctionalized 3-cyclopentenes. High yield synthesis of 3-cyclopentenecarboxylic acid

[Depres, Jean-Pierre; Greene, Andrew E. Journal of Organic Chemistry, 1984 , vol. 49, # 5 p. 928 - 931]

More Articles...