Cyclo-ruthenated and-platinated complexes bearing phosphonate substituents

…, DM Tooke, AL Spek, GPM van Klink, G van Koten

Index: Wadman, Sipke H.; Tooke, Duncan M.; Spek, Anthony L.; van Klink, Gerard P.M.; van Koten, Gerard Inorganica Chimica Acta, 2010 , vol. 363, # 8 p. 1701 - 1706

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Citation Number: 4

Abstract

Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N^ C (H)^ N (5) and Et2O3P-C (H)^ N^ N (7), have been prepared. The corresponding ruthenium complexes,[1]+ and [2]+, respectively, were obtained by reaction with [RuCl3 (tpy)]. Complexes [1]+ and [2]+ display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N^ C (H)^ N ligand 5, ...