Reactions of 1, 1-diarylethylenes and 1, 1-diarylimines with CF3OF

TB Patrick, GL Cantrell, SM Inga

Index: Patrick, Timothy B.; Cantrell, Gary L.; Inga, Sandra M. Journal of Organic Chemistry, 1980 , vol. 45, # 8 p. 1409 - 1413

Full Text: HTML

Citation Number: 33

Abstract

1, l-Diphenylethylene (1) reacts with CF, OF to give products 2-6 in a cationic process. 9- Ethylidenefluorene reacts with CF30F to yield 8 and 10. Amitriptyline (12) furnished a difluoro adduct (13) in low yield. Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF30F. Fluorenone ani1 (15) produced mainly fluorenone from reaction with CF30F. Diazepam (16) gave a 1: l adduct (18) with CF30F. ...

Related Articles:

Monofluorovinyl Tosylate: A Useful Building Block for the Synthesis of Terminal Vinyl Monofluorides via Suzuki− Miyaura Coupling

[Zhang, He; Zhou, Chang-Bing; Chen, Qing-Yun; Xiao, Ji-Chang; Hong, Ran Organic Letters, 2011 , vol. 13, # 4 p. 560 - 563]

N-Fluorobis [(perfluoroalkyl) sulfonyl] imides: reactions with some olefins via. alpha.-fluoro carbocationic intermediates

[DesMarteau, Darryl D.; Xu, Ze-Qi; Witz, Michael Journal of Organic Chemistry, 1992 , vol. 57, # 2 p. 629 - 635]

A novel and efficient synthesis of fluoromethyl phenyl sulphone and its use as a fluoromethyl Wittig equivalent

[Inbasekaran, Muthiah; Peet, Norton P.; McCarthy James R.; LeTourneau, Michael E. Journal of the Chemical Society, Chemical Communications, 1985 , # 10 p. 678 - 679]

N-Fluorobis [(perfluoroalkyl) sulfonyl] imides: reactions with some olefins via. alpha.-fluoro carbocationic intermediates

[DesMarteau, Darryl D.; Xu, Ze-Qi; Witz, Michael Journal of Organic Chemistry, 1992 , vol. 57, # 2 p. 629 - 635]

The reaction of XeF 2 with trialkylvinylstannanes: scope and some mechanistic observations

[Tius, Marcus A.; Kawakami, Joel K. Tetrahedron, 1995 , vol. 51, # 14 p. 3997 - 4010]

More Articles...