Reaction of [cyclotetraphosphine](CF3P) 4 with some compounds with nonmetal-nonmetal bonds

AH Cowley, DS Dierdorf

Index: Cowley,A.H.; Dierdorf,D.S. Journal of the American Chemical Society, 1969 , vol. 91, p. 6609 - 6613

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Citation Number: 17

Abstract

Abstract: The cyclotetraphosphine (CF3P) 4 reacts with (CH3) 4As2 and (CH&Sz to insert a CF3P group into the As-As or SS bond. A variety of products was formed by the action of (CFQ)(on (CH3) 2NP (CH3) 2 with the major component being the phosphinidene complex (CH3); N (CH3), P-PCF3. Tetramethylhydrazine behaves like (CH3) 3N in that it catalyzes the interconversion of (CF3P), and (CF3P) s. However, no NN bond cleavage was ...