Oxidative Addition of N-Aminophthalimide to Conjugated and Nonconjugated Alkylazoalkanes

MA Kuznetsov, VN Belov, SM Buchaka

Index: Kuznetsov; Belov; Buchaka Russian Journal of Organic Chemistry, 2005 , vol. 41, # 2 p. 204 - 213

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Citation Number: 3

Abstract

Abstract A series of γ, δ-unsaturated azo compounds was prepared by thermal isomerization of allylalkylhydrazones obtained from the simplest carbonyl compounds. The oxidation of N- aminophthalimide with lead tetraacetate in the presence of these unsaturated compounds gave rise to mixtures of adducts at the azo group, regioisomers of phthalimidoazimines. The oxidative addition of N-aminophthalimide to 1-isopropylazocycloalkenes afforded bicyclic ...