A new and simple method for the synthesis of highly functionalised pyrrolizidines, indolizidines and pyrroloazepines

PA O'Gorman, T Chen, HE Cross, S Naeem, A Pitard…

Index: O'Gorman, Paul A.; Chen, Ting; Cross, Hannah E.; Naeem, Saleena; Pitard, Arnaud; Qamar, M. Ilyas; Hemming, Karl Tetrahedron Letters, 2008 , vol. 49, # 44 p. 6316 - 6319

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Citation Number: 16

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The reaction of 5-, 6- and 7-membered cyclic thioimidates with cyclopropenones gives access to highly functionalised pyrrolizidines, indolizidines and pyrroloazepines via a formal [3+2] cycloaddition process. ... Cyclopropenones react with cyclic thioimidates to give indolizidine and pyrrolizidine ...

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