Transfer Reactions Involving Boron. VI. Physical Characterization and Chemical Properties of Aryl-and Alkylthioboranes1, 2

DJ Pasto, CC Cumbo…

Index: Pasto,D.J. et al. Journal of the American Chemical Society, 1966 , vol. 88, p. 2187 - 2194

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Citation Number: 22

Abstract

Abstract: The reaction of thiophenol with borane in tetrahydrofuran produces monomeric phenylthioborane. The structure of phenylthioborane was deduced from infrared and boron- 1 1 magnetic resonance spectral data and molecular weight measurements. In contrast, benzyl mercaptan reacts with borane in tetrahydrofuran to produce a polymeric benzylthioborane. Aryl-and alkylthioboranes have been found to be effective ether ...