Synthesis and structures of the dinuclear tin (II) complexes [R= Ph, X (Z)= CPh; R= SiMe 3, X (Z)= PPh 2] and of related compounds

PB Hitchcock, MF Lappert, M Linnolahti…

Index: Hitchcock, Peter B.; Lappert, Michael F.; Linnolahti, Mikko; Severn, John R.; Uiterweerd, Patrick G.H.; Wang, Zhong-Xia Journal of Organometallic Chemistry, 2009 , vol. 694, # 21 p. 3487 - 3499

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Citation Number: 4

Abstract

Tin (II) compounds containing the ligands [CH (C6H3Me2-2, 5) C (But) NSiMe3]−(≡ L1),[CH (Ph) C (Ph) NSiMe3]−(≡ L2),[CH (SiMe3) P (Ph) 2NSiMe3]−(≡ L3),(≡ L4),[C (Ph) C (Ph) NSiMe3] 2−(≡ L5), and [C (SiMe3) P (Ph) 2NSiMe3] 2−(≡ L6) are reported: the transient SnBr (L1)(1) and SnBr (L2)(2), Sn (L1) 2 (3)[PB Hitchcock, J. Hu, MF Lappert, M. Layh, JR Severn, J. Chem. Soc., Chem. Commun.(1997) 1189], the labile Sn (L2) 2 (4),[Sn (L5)] 2 (5 ...