Oxidative deamination of primary amines: selective synthesis of geminal dihalides

MP Doyle, B Siegfried

Index: Doyle,M.P.; Siegfried,B. Journal of the Chemical Society, Chemical Communications, 1976 , p. 433 - 434

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Abstract

SELECTIVE oxidative conversion of unbranched primary amines into aldehydes or aldehyde derivatives has not previously been achieved. Two approaches to this problem are envisaged : dehydrogenation of amines, and oxidative deamination. Considerable interest has recently been focused on the dehydrogenation of amine ligands in pro- moting amine oxidations by transition nieta1s.l However, dehydrogenation of unbranched primary amines does not terminate at ...

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