Comparison of hydrogen bonding abilities of some organic compounds of phosphorus

GM Kosolapoff, JF McCullough

Index: Kosolapoff; McCullough Journal of the American Chemical Society, 1951 , vol. 73, p. 5392

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Citation Number: 33

Abstract

The maximum heats of mixing of chloroform with fifteen organophosphorus compounds were determined. Representative members of the families of types: RzP (O) OR, RP (O)(ORh,(RO) $ PO,(RO) zP (OjCI, ROP (O) Cl+(RO) aP and (RO) z-POH display differences in their hydrogen bonding ability, as reflected by the heat of mixing. These differences are qualitatively predictable from the structures of the compounds, showing enhanced activity ...