Synlett

Potential supramolecular cyclodextrin dimers using nucleobase pairs

…, F Turpin, M Bellot, L Bouteiller, F Djedaini-Pilard…

Index: Hamon, Florian; Violeau, Bruno; Turpin, Frederic; Bellot, Mathilde; Bouteiller, Laurent; Djedaini-Pilard, Florence; Len, Christophe Synlett, 2009 , # 17 p. 2875 - 2879

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Citation Number: 8

Abstract

Abstract The synthesis of six new cyclodextrin derivatives having nucleobase moiety is described. These two moieties are linked by different spacers, such as aminoethyl and 1, 2, 3-triazolyl groups. Example of association constants for complexation of adenine and thymine derivatives: K AT= 385 M-¹ using NMR methodology is reported. Study of interaction between four cyclodextrin derivatives and one adamantyl guest is described by ITC.

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