Zirconium-catalyzed highly regioselective carbon-carbon bond formation reactions

…, DY Kondakov, T Takahashi

Index: Suzuki, Noriyuki; Kondakov, Denis Y.; Takahashi, Tamotsu Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8485 - 8486

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Citation Number: 60

Abstract

Recently Zr-catalyzed CC bond formation reactions via Zralkene complexes have been reported. 2 For allylic compounds, catalytic CC bond formation using the Cp2ZrC12lEtMgBr system proceeded at the,% carbon of allylic compounds. 2a-cd To the best of our knowledge, however, the Zr-catalyzed allylation reaction (eq 1) has not been successful using this system. 3