Photochemistry of diastereomeric 2, 4-diphenylpentan-3-ones and related ketones in" super-cage" environments provided by micelles, porous glass, and porous silica …

BH Baretz, NJ Turro

Index: Baretz,B.H.; Turro,N.J. Journal of the American Chemical Society, 1983 , vol. 105, p. 1309

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Citation Number: 58

Abstract

Conclusion The fixation reaction of carbon dioxide with a (porphinat0)-aluminum alkoxide was first investigated by the spectroscopic methods using (tetrapheny1porphinato) aluminum alkoxide having a long oxyalkylene chain as an alkoxide group, taking advantage of the good solubility. This alkoxide with unique structure was found to behave as a “carrier” of carbon dioxide activated enough to react under mild conditions with epoxide in the ...