Palladium??Catalyzed Carbonylation of Amines: Switchable Approaches to Carbamates and N, N′??Disubstituted Ureas

…, M Chen, ZH Ren, Y Bai, YY Wang

Index: Guan, Zheng-Hui; Lei, Hao; Chen, Ming; Ren, Zhi-Hui; Bai, Yinjuan; Wang, Yao-Yu Advanced Synthesis and Catalysis, 2012 , vol. 354, # 2-3 p. 489 - 496

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Citation Number: 30

Abstract

Abstract Switchable access to carbamates and ureas has been developed by solvent control palladium-catalyzed carbonylation of aromatic amines under an atmosphere of carbon monoxide. A variety of N-phenylcarbamates and N, N′-diphenylureas was easily synthesized in good to excellent yields from readily available aromatic amines under mild conditions.

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