Palladium-catalyzed cross-carbonylation of aryl iodides with five-membered cyclic olefins

…, T Itaya, K Okuro, M Miura, M Nomura

Index: Satoh, Tetsuya; Itaya, Tomoaki; Okuro, Kazumi; Miura, Masahiro; Nomura, Masakatsu Journal of Organic Chemistry, 1995 , vol. 60, # 22 p. 7267 - 7271

Full Text: HTML

Citation Number: 38

Abstract

Intermolecular cross-carbonylation of aryl iodides with five-membered cyclic olefins such as dihydrofurans and cyclopentene was found to proceed by using a catalyst system of PdClflPh3 under CO (3-5 atm) in the presence of a tertiary amine. With 2, 3-and 2, 5- dihydrofurans, 2-aroyl-4, 5-dihydro-and 3-aroyl-2, 3-dihydrofans were obtained as the predominant products, respectively, while the reaction of iodobenzene with cyclopentene ...

Related Articles:

Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations

[Wdowik, Tomasz; Samojlowicz, Cezary; Jawiczuk, Magdalena; Malinska, Maura; Wozniak, Krzysztof; Grela, Karol Chemical Communications, 2013 , vol. 49, # 7 p. 674 - 676]

A new, efficient approach to α, β-unsaturated ketones and β-hydroxy ketones from 4, 5-dihydroisoxazoles

[Kwiatkowski, Stefan Journal of the Chemical Society, Chemical Communications, 1987 , # 19 p. 1496 - 1498]

1, 2??Addition of α, α, α??Trichlorotoluene to Ketones via a Mg Barbier Reaction in DMF: New Route to Cycloalk??1??en??1??yl and Alk??1??en??1??yl Phenyl Ketones

[Aaziz, Akima; Oudeyer, Sylvain; Leonel, Eric; Paugam, Jean Paul; Nedelec, Jean-Yves Synthetic Communications, 2007 , vol. 37, # 7 p. 1147 - 1154]

Cathodic addition of benzylidyne trichloride to ketones and aldehydes.

[Steiniger, Michael; Schaefer, Hans J. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 1 p. 125 - 132]

Cyclopropanes. XX. 1 1-Benzoyl-6-nitrobicyclo [3, 1, 0] hexane: Behavior toward Alkaline Reagents

[Smith; Scribner Journal of the American Chemical Society, 1956 , vol. 78, p. 3412,3415]

More Articles...