Journal of organometallic chemistry

Reaction of dialkylmagnesium with carbon monoxide. II

P Sobota, M Nowak

Index: Sobota, Piotr; Nowak, Marek Journal of Organometallic Chemistry, 1988 , vol. 340, p. 1 - 6

Full Text: HTML

Citation Number: 4

Abstract

Abstract Reaction of MgEt 2 with CO gives Et 2 CO, Et 2 CHOH, EtCOCH (OH) Et, EtCOCHEt 2 and EtCOC (OH) Et 2. The qualitative and quantitative composition of the product mixture was found to be dependent on the MgEt 2 concentration and the polarity of solvent. The kinetic results reveal that reaction of CO with MgEt 2 and with its dissociation product MgEt 3−, followed by the formation of the Et 2 CO and EtCOCHEt 2, respectively. The other ...

Related Articles:

Origin of. alpha.-Hydroxy Ketones in the Osmium Tetroxide-Catalyzed Asymmetric Dihydroxylation of Alkenes

[Lohray, Braj B.; Bhushan, Vidya; Kumar, R. Krishna Journal of Organic Chemistry, 1994 , vol. 59, # 6 p. 1375 - 1380]

1, 4, 5-trialkyl imidazole system anti-inflammatory properties of new substituted derivatives.

[Fatimi; Lagorce; Duroux; Chabernaud; Buxeraud; Raby Chemical and Pharmaceutical Bulletin, 1994 , vol. 42, # 3 p. 698 - 701]

Die Umsetzung von carbonsäureestern mit natrium in gegenwart von trimethylchlorsilan

[Ruehlmann,K. Synthesis, 1971 , p. 236 - 253]

Elemental fluorine. Part 7. New oxidation methodology

[Chambers, Richard D.; Hutchinson, John; Sandford, Graham; Shah, Aneela; Vaughan, Julian F. S. Tetrahedron, 1997 , vol. 53, # 46 p. 15833 - 15842]

Photochemical Reactions of 1, 2-Diketones

[Urry,W.H.; Trecker,D.J. Journal of the American Chemical Society, 1962 , vol. 84, p. 118 - 120]

More Articles...