Enantioselective synthesis of 1-arylethanediols by rhodium-catalyzed transfer hydrogenation of α-tosyloxyarylketones
DM Lee, G Kumaraswamy, KI Lee
Index: Lee, Do-Min; Kumaraswamy, Gullapalli; Lee, Kee-In Monatshefte fur Chemie, 2009 , vol. 140, # 1 p. 73 - 78
Full Text: HTML
Citation Number: 4
Abstract
Abstract Catalytic transfer hydrogenation of α-tosyloxyarylketones mediated by a chiral rhodium complex using an azeotropic mixture of formic acid/triethylamine afforded the corresponding 1-arylethanediol monotosylates in excellent yield with high enantioselectivity.
Related Articles:
[Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806]
[Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806]
[Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806]
[Mizuno, Masashi; Kanai, Motomu; Iida, Akira; Tomioka, Kiyoshi Tetrahedron, 1997 , vol. 53, # 31 p. 10699 - 10708]