Kinetic study on the alkaline hydrolysis of 1??aryl??2??phenyl??2??imidazolines. Basicity??rate of hydrolysis and structure relationships

…, AM Reverdito, S Lamdan

Index: Fernandez, Beatriz M.; Reverdito, Ana M.; Lamdan, Samuel Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 933 - 937

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Abstract

Abstract Rate constants (k obs) of hydrolysis in boiling alkaline ethanolic solution for six 1- aryl-2-phenyl-2-imidazolines were determined. The influence of substituents in the phenyl group at N-1 upon rate of hydrolysis was studied. When the imidazoline ring is considered to be a substituent of the benzene ring at N-1, a good correlation with the Hammett equation is found. It was observed that reaction rates were enhanced by electron-releasing phenyl ...

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