Functional hybrid materials based on layered simple hydroxide hosts and dicarboxylate Schiff base metal complex guests

S Eyele??Mezui, E Delahaye, G Rogez…

Index: Eyele-Mezui, Seraphin; Delahaye, Emilie; Rogez, Guillaume; Rabu, Pierre European Journal of Inorganic Chemistry, 2012 , # 32 p. 5225 - 5238

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Citation Number: 6

Abstract

Abstract The insertion of carboxysalen-type complexes into magnetic layered transition- metal simple hydroxides has provided new hybrid compounds. Three kinds of carboxysalen ligands have been used: an ethylenediamine bridge (SED-H 2), a chiral cyclohexanediamine bridge [(S, S)-SCD-H 2 and (R, R)-SCD-H 2], and an aromatic o- phenylenediamine bridge (SBD-H 2). The ccorresponding Cu II, Ni II, Co II, Zn II, Mn III, ...