A novel electrochemical method for benzoylation of aminoalcohols with methyl benzoates at room temperature

…, T Masumizu, KI Kawai, S Nakajima…

Index: Arai, Kenji; Tamura, Shohei; Masumizu, Tatsuya; Kawai, Ken-Ichi; Nakajima, Shoichi; Ueda, Akira Canadian Journal of Chemistry, 1990 , vol. 68, # 6 p. 903 - 907

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Citation Number: 6

Abstract

A novel electrochemical method of benzoylating aminoalcohols 2 by use of methyl benzoates 1 at room temperature was developed. 2-Aminoethanols 2 (n= 0, R3= H) and 3- aminopropanols 2 (n= 1, R3= H) gave the corresponding benzamides 4, as a result of electrochemical transesterification followed by O, N-actyl migration. In contrast, o-and m- aminobenzylalcohols (7 a and 7 b) and trans-4-(aminomethyl) cyclohexanemethanol (8 a) ...

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