A general and efficient catalyst for palladium-catalyzed C− O coupling reactions of aryl halides with primary alcohols

S Gowrisankar, AG Sergeev, P Anbarasan…

Index: Gowrisankar, Saravanan; Sergeev, Alexey G.; Anbarasan, Pazhamalai; Spannenberg, Anke; Neumann, Helfried; Beller, Matthias Journal of the American Chemical Society, 2010 , vol. 132, # 33 p. 11592 - 11598

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Citation Number: 104

Abstract

An efficient procedure for palladium-catalyzed coupling reactions of (hetero) aryl bromides and chlorides with primary aliphatic alcohols has been developed. Key to the success is the synthesis and exploitation of the novel bulky di-1-adamantyl-substituted bipyrazolylphosphine ligand L6. Reaction of aryl halides including activated, nonactivated, and (hetero) aryl bromides as well as aryl chlorides with primary alcohols gave the ...

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