Oxidation of α-hydroxy containing monoterpenes using titanium silicate catalysts: comments on regioselectivity and the role of acidity

LJ Schofield, OJ Kerton, P McMorn, D Bethell…

Index: Schofield, Lee J.; Kerton, Owain J.; McMorn, Paul; Bethell, Donald; Ellwood, Simon; Hutchings, Graham J. Journal of the Chemical Society, Perkin Transactions 2, 2002 , # 8 p. 1475 - 1481

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Citation Number: 19

Abstract

The regioselective epoxidation of monoterpenes in the liquid phase has been studied using the titanosilicates TS-1 and TiAlβ. A range of oxidants (hydrogen peroxide, tert-butyl hydroperoxide and urea–hydrogen peroxide complex) have been studied in detail. The allylic alcohols linalool and geraniol have been studied alongside the non-allylic alcohol citronellol and the diene dihydromyrcene to help determine the role of the hydroxy group ...

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Large pore bifunctional titanium–aluminosilicates: the inorganic non-enzymatic version of the epoxidase conversion of linalool to cyclic ethers

[Corma, A.; Iglesias, M.; Sanchez, F. Journal of the Chemical Society, Chemical Communications, 1995 , # 16 p. 1635 - 1636]

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[Santos, Isabel C.M.S.; Balula, Salete S.; Simoes, Mario M.Q.; Cunha-Silva, Luis; Neves, M. Graca P.M.S.; De Castro, Baltazar; Cavaleiro, Ana M.V.; Cavaleiro, Jose A.S. Catalysis Today, 2013 , vol. 203, p. 87 - 94]

Catalytic performance of a boron peroxotungstate complex under homogeneous and heterogeneous conditions

Oxidation of α-hydroxy containing monoterpenes using titanium silicate catalysts: comments on regioselectivity and the role of acidity

Abstract

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