Photolysis of Alkynyl (phenyl) iodonium Salts. Remarkable Solvent Effect and Generation of Acids.

T Kitamura, T Tanaka, H Taniguchi

Index: Kitamura, Tsugio; Tanaka, Toshimasa; Taniguchi, Hiroshi Chemistry Letters, 1992 , # 11 p. 2245 - 2248

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Citation Number: 5

Abstract

Photolysis of alkynyl (phenyl) iodonium salts in CH 2 Cl 2 resulted in major formation of iodobenzene, while the photolysis in EtOH, Et 2 O, or THF gave iodoalkynes as the main product. In addition to the organic products, acids were generated almost quantitatively by the photolysis and initiated polymerization of styrene.