Synthesis of Functionalized trans??A2B2??Porphyrins Using Donor–Acceptor Cyclopropane??Derived Dipyrromethanes

MH Beyzavi, C Nietzold, HU Reissig…

Index: Beyzavi, M. Hassan; Nietzold, Carolin; Reissig, Hans-Ulrich; Wiehe, Arno Advanced Synthesis and Catalysis, 2013 , vol. 355, # 7 p. 1409 - 1422

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Citation Number: 13

Abstract

Abstract meso-Substituted trans-A 2 B 2-porphyrins bearing specific patterns of substituents are crucial building blocks in porphyrin-based biomimetic systems and molecular materials and can be used for the construction of well-defined porphyrin-based architectures. A new stepwise and rational synthesis of functionalized trans-A 2 B 2-porphyrins is reported in which for the first time donor–acceptor-substituted cyclopropane precursors (d–a ...

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